Butane-1,4-diaminium 2-(methoxycarbonyl)benzoate dihydrate

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Butane-1,4-diaminium 2-(meth­oxy­carbon­yl)benzoate dihydrate

In the title compound, C(4)H(14)N(2) (+)·2C(9)H(7)O(4) (-)·2H(2)O, the butane-1,4-diaminium cation lies on an inversion center. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the components into layers parallel to (100). Addtional stabilization within these layers is provided by weak inter-molecular C-H⋯O hydrogen bonds.

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Butane-1,4-diaminium bis­[3,4,5,6-tetra­chloro-2-(meth­oxy­carbon­yl)benzoate]

In the title salt, C(4)H(14)N(2) (+)·2C(9)H(3)Cl(4)O(4) (-), the cation lies on an inversion center. In the anion, the mean planes of meth-oxy-carbonyl and carboxyl-ate groups form dihedral angles of 64.9 (3) and 58.5 (3)°, respectively, with the benzene ring. In the crystal, inter-molecular N-H⋯O hydrogen bonds connect the components into sheets parallel to (100).

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Ethane-1,2-diaminium dipicrate dihydrate

The title compound, C(2)H(10)N(2) (2+)·2C(6)H(2)N(3)O(7) (-)·2H(2)O, crystallizes with a complete picrate anion and half an ethyl-enediammonium dication on a mirror plane, and two half-water mol-ecules (both on a mirror plane) in the asymmetric unit. The N atoms from separate half ethyl-enediammonium dications are in near proximity to a phenolate O atom and two o-NO(2) groups from the picrate a...

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Butane-1,2,3,4-tetra­carboxylic acid dihydrate

The asymmetric unit of the title compound, C(8)H(10)O(8)·2H(2)O, contains one half-mol-ecule of butane-1,2,3,4-tetra-carboxylic acid and a water mol-ecule, with the complete tetra-acid generated by crystallographic inversion symmetry. Inter-molecular O-H⋯O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal packing.

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1,1′-(Butane-1,4-di­yl)dipyridinium dibromide dihydrate

The organic cation in the title compound, C(14)H(18)N(2) (2+)·2Br(-)·2H(2)O, is situated on an inversion centre. The cations, anions and water mol-ecules are linked via O-H⋯Br, C-H⋯Br and C-H⋯O hydrogen bonds, and π-π stacking inter-actions between adjacent pyridine rings, with a centroid-centroid separation of 3.8518 (17) Å.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811003618